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<datacite:alternateIdentifier>
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https://figshare.com/articles/Superior_Charge_Storage_and_Power_Density_of_a_Conducting_Polymer-Modified_Covalent_Organic_Framework/3762531
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<datacite:alternateIdentifier>10.1021/acscentsci.6b00220.ls01</datacite:alternateIdentifier>
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<datacite:titles>
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<datacite:title>Superior Charge Storage and Power Density of a Conducting Polymer-Modified Covalent
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Organic Framework
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192
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</datacite:title>
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193
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</datacite:titles>
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<datacite:descriptions>
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<datacite:description descriptionType="Abstract">The low conductivity of two-dimensional covalent
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organic frameworks (2D COFs), and most related coordination polymers, limits their applicability in
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optoelectronic and electrical energy storage (EES) devices. Although some networks exhibit promising
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conductivity, these examples generally lack structural versatility, one of the most attractive
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features of framework materials design. Here we enhance the electrical conductivity of a
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redox-active 2D COF film by electropolymerizing 3,4-ethylenedioxythiophene (EDOT) within its pores.
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The resulting poly(3,4-ethylenedioxythiophene) (PEDOT)-infiltrated COF films exhibit dramatically
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improved electrochemical responses, including quantitative access to their redox-active groups, even
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for 1 μm-thick COF films that otherwise provide poor electrochemical performance. PEDOT-modified COF
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films can accommodate high charging rates (10–1600 C) without compromising performance and exhibit
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both a 10-fold higher current response relative to unmodified films and stable capacitances for at
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least 10 000 cycles. This work represents the first time that electroactive COFs or crystalline
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framework materials have shown volumetric energy and power densities comparable with other porous
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carbon-based electrodes, thereby demonstrating the promise of redox-active COFs for EES devices.
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</datacite:description>
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</datacite:descriptions>
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<datacite:subjects>
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<datacite:subject>Power Density</datacite:subject>
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<datacite:subject>redox-active 2 D COF film</datacite:subject>
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<datacite:subject>EES devices</datacite:subject>
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<datacite:subject>Biotechnology</datacite:subject>
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<datacite:subject>redox-active groups</datacite:subject>
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<datacite:subject>power densities</datacite:subject>
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<datacite:subject>redox-active COFs</datacite:subject>
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<datacite:subject>framework materials</datacite:subject>
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220
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<datacite:subject>Space Science</datacite:subject>
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221
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<datacite:subject>electroactive COFs</datacite:subject>
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222
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<datacite:subject>conductivity</datacite:subject>
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<datacite:subject>energy storage</datacite:subject>
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<datacite:subject>framework materials design</datacite:subject>
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225
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<datacite:subject>Biophysics</datacite:subject>
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226
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<datacite:subject>Immunology</datacite:subject>
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<datacite:subject>coordination polymers</datacite:subject>
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<datacite:subject>networks exhibit</datacite:subject>
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229
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<datacite:subject>PEDOT-modified COF films</datacite:subject>
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<datacite:subject>10 000</datacite:subject>
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<datacite:subject>1 μ m-thick COF films</datacite:subject>
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232
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<datacite:subject>Medicine</datacite:subject>
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233
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<datacite:subject>Superior Charge Storage</datacite:subject>
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234
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<datacite:subject>Conducting Polymer-Modified Covalent Organic Framework</datacite:subject>
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<datacite:subject>carbon-based electrodes</datacite:subject>
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<datacite:subject>10 000 cycles</datacite:subject>
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<datacite:subject
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subjectScheme="http://www.abs.gov.au/ausstats/abs@.nsf/0/6BB427AB9696C225CA2574180004463E">39999
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Chemical Sciences not elsewhere classified
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</datacite:subject>
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241
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<datacite:subject>electrochemical responses</datacite:subject>
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242
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<datacite:subject>electrochemical performance</datacite:subject>
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</datacite:subjects>
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<datacite:date dateType="Issued"/>
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<datestamp>2019-03-27T15:05:19Z</datestamp>
|
|
257
|
<metadataNamespace>http://schema.datacite.org/oai/oai-1.0/</metadataNamespace>
|
|
258
|
</originDescription>
|
|
259
|
</provenance>
|
|
260
|
</oai:about>
|
|
261
|
</oai:record>
|